Types of Acids and Bases:
Arrhenius: acids and bases dissolve
in water releasing H+ and OH- respectively.
This is a narrow categorization.
Bronsted-Lowry: an acid is a H+
donor, and a base is a H+ acceptor. This is also a
narrow definition, but a very important one.
Lux-Flood: an acid is an O2-
acceptor, and a base is an O2- donor. This is an important
definition in geological terms, where the chemistry of aluminosilicates
is very important.
Lewis: an acid is an electron pair
acceptor, and a base is an electron pair donor. This is the most
general definition of the acid-base interaction, and covers all
of coordination chemistry, and the HOMO to LUMO transitions.
Bronsted Acidity: The acid is a
proton donor, and equilibria are set up in aqueous solution:
| The acid is HF, and the base
is H2O |
 |
| The acid is H2O,
and the base is NH3 |
 |
Here we see that water can act as both the acid
and the base. This kind of substance is called amphiprotic.
It should be noted that proton transfer is rapid
in both directions, and the deprotonation of the HF or H2O,
and acid-base chemistry in general, is best described as rapidly
attained proton transfer equilibria.
Conjugate acids and bases:
In the first equilibrium above, H3O+
is a bronsted acid in the reverse reaction as it donates a
proton to F-. Hence, F- is a bronsted
base, as it is a proton acceptor. Similarly in the reverse
reaction of the second equilibrium, NH4+
is a bronsted acid and OH- is a bronsted base.
The general equilibrium can be written for the
proton transfer reaction:
The species Base1 is called the conjugate base
of Acid1 (eg. Base1 is F-
for acid1 is HF), and the species Acid2
is known as the conjugate acid of Base2 (eg.
Acid2 is H3O+ for Base2
is H2O).
It should be noted that there is no fundamental difference
between an acid and a conjugate acid or a base and a conjugate
base: the conjugate base and conjugate acid are just the
products of the reaction of the original acid and base.
|