Water is the most common solvent with respect to acids and bases.
Often, the critical factor in determining the strength of an acid
is played by the solvent, especially when that solvent is water.
Unfortunately, given that water is an ionising solvent, many organic
acids do not dissolve sufficiently in it to begin with. However,
if that hurdle is cleared, water is very effective as an ionising
solvent, as it has a very high dielectric
constant, and a high ion-solvating ability.
A high dielectric constant means that the force of attraction between
any two oppositely charged ions will be lower than if they were
in a solvent of low dielectric constant. Therefore, as the
energy required to break them apart is less, they will be more stable
in solution, and also less likely to recombine.
The ion-solvating ability helps, because ions in solution polarise
their neighbouring solvent molecules, which stick to them in a semi-rigid
frame, known as a solvent cage.
Water is excellent at being polarised, and fairly small, and hence
readily solvates anions and cations. e.g.:
The actual number of solvating molecules depends on
many factors, such as the size and charge of the ion, the size of
the solvent molecules, their ease of polarisability, and their shape.
The diagrams above are for illustrative purposes only.
One of the primary functions of the solvent, however,
is that it should be able to function as a base (if an acid is in
solution). The less basic the solvent, the less dissociated
the acid.
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