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Previously, we saw the construction of a sigma bond in ethane from
two sp3 hybridised orbitals. However, although
sp3 hybridisation is perhaps the most common form, it
is certainly not the only form of hybridisation available to carbon.
Now let us take a look at sp2 hybridisation: As
the name indicates, this is hybridisation involving one s orbital,
and two p orbitals.

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The image to the left illustrates that there are three sp2
orbitals, and one unhybridised p orbital. The three hybrid
orbitals are separated by angles of 120°, i.e. they describe the
points of an equilateral triangle. The p orbital lies perpendicular
to the plane of that triangle, with equal sized lobes above and
below the plane.From above, they look like the image in the right.
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Here we can see more clearly the triangular displacement
of the hybrid orbitals.
This arrangement of sp2 orbitals allows
us to explain some of the observed features of ethene. It
was known for a long time that in order for the carbon atoms in
ethene to be tetravalent (to accept four electrons into its valence
shell), they must share a total of four electrons (thus we
have 4 valence electrons plus 1 from each hydrogen plus two from
the other carbon, which equals 8). It is not easy to imagine
this without the use of hybridised orbitals. However, let
us imagine two CH2 fragments, with an sp2
carbon in each:
Now, as we bring them closer together, it is obvious
that there will be overlap of one of the sp2 orbitals
from each fragment. This forms a sigma bond as before in ethane.
However, there will also be overlap of the unhybridised p orbitals
above and below the plane of the molecule, to from a pi bond:
This combination of sigma and pi bond is known as
a double bond. It is important to note that the use of hybridised
orbitals has automatically predicted that ethene is planar, which
it is, and we might also imagine that ethene will not twist about
its C-C axis, because to do so will destroy the pi bond, which will
be energetically unfavourable. This is indeed the case.
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