A carbonyl is a molecule containing the C=O functional group.
For the purposes of this chapter they will be split into 2 categories
- one category will be ketones and aldehydes, the other will include
pretty much everything else.
To see how this breaks down;

Of the latter class a couple of examples have been given - some
other important carbonyls from this group are shown below;
The reason for splitting the carbonyls up like this is that they
display 2 different reactivity types - you may have noticed that
the second class differs from the first class in that they all
have some sort of leaving group, whereas the ketones/aldehydes
do not. Because of their LG, the second class can undergo nucleophilic
substitutions, which were referred to here.
This general reaction is pictured below, with the leaving group
demoted X;

In some cases this will require perhaps acid or base catalysis
to make it go - an example of this is the amide; -NH2
is a very poor leaving group, but if is protonated it is much
better.
In terms of general reactivity towards nucleophiles, the trend
is with how good the leaving group is;
Acid Chloride > Anhydride > Ester ~ Carboxylic
Acid > Amide
At the right hand end of the scale, the carbonyls are made less
reactive by resonance donation from their X group into the carbonyl
π system - shown here for the amide;

This delocalised π system holds the
amide in a planar conformation - another way to put this is to
say there is partial double bond character between the carbon
and the nitrogen (although the majority of the double bond is
still between the carbon and the oxygen). The effect of π
donation into the C=O system is to lessen the polarity of the
bond and make it less attractive to incoming nucleophiles.
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