There are four major categories into which organic reactions fall.
These are:
- Substitution
- Addition
- Elimination
- Rearrangement
Substitution
To deal with 1. first, substitution usually occurs
on carbon. There are two sub-categories of this type: nucleophilic,
and electrophilic.
This is an example of electrophilic substitution (nitration
of benzene):
Below is a characteristic example of nucleophilic
substitution:

NC- is the nucleophile in this case.
Addition
Addition reactions are also sub-categorised into nucleophilic
and electrophilic reactions. They can also be radical.
For example, the addition to C-C double bonds is usually an electrophilic
or radical process. e.g.:
This can either be initiated by attack of H+
or Br- on the double bond. However, the addition
reactions to carbonyl groups (e.g. in either aldehydes or ketones)
are nucleophilic. e.g.:
Elimination
Elimination reactions are essentially addition reactions
running backwards. e.g.: |
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Rearrangements
Rearrangements can occur via intermediates that closely
resemble cations, anions or radicals. However, normally we
find that rearrangements occur via carbocations. During a
rearrangement, as the name indicates, it is possible to change the
carbon skeleton significantly. e.g.: the Pinacol rearrangement
All these reactions will be dealt with in more detail
elsewhere.
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