It is important not to lose track of the basic principles of
activity amongst all the detailed derivations of the equations.
Thus it is appropriate to provide here a brief summary of the
salient points of the previous two pages:
Activities are an adjusted form of the mole fraction (or molality
or concentration) of a species in a solution, be it the solvent
or solute. The adjustment is required to take into account
the interactions between molecules in solution, which can
alter the extent to which they are free to participate in reaction.
Activities are commonly written as an activity coefficient,
γ, multiplying the mole fraction
(or molality) that the activity is to replace. These coefficients
change with the composition of the solution.
Solvents
For a solvent which is the component in excess
in a two species mixture, we define the standard state as the
pure liquid. The chemical potential of the pure liquid is given
the symbol μ*. The chemical potential of the solvent
at any composition is given by:

In this instance, the activity is defined in two ways. It is
used in calculations as:

and it must be noted that as the mole fraction tends to one
(as the purity of the liquid increases) the activity coefficient
also tends to one (the deviations from ideality in the solvent's
behaviour decrease, and its behaviour becomes more in line with
Raoult's Law).
The activity of a solvent may be measured experimentally using
the other definition:

Solutes
For a solute there are two different approaches.
The first method defines the standard state of the solute as
a hypothetical state of the pure solute. This does not mean
it is defined as the pure state of the solute, but as a state
with different properties to the pure state (eg a different
chemical potential) that behaves as a pure liquid in certain
situations. The chemical potential of this standard state is
given the symbol μ#. The chemical potential
of the solute at any composition is now given by:

The activity is again defined in two ways. The first definition
is the same as for the solvent case:

but for the solute, the activity coefficient tends to one as
the mole fraction tends to zero. i.e. the more dilute the solution,
the more in accord with Henry's Law is the behaviour of the
solute.
The activity of the solute may be measured from its second definition:

where K is the Henry's Law constant for the solute.
The second method for dealing with the solute defines the standard
state as a hypothetical state of the solute when its molality
is bº (1 mol kg-1). The chemical
potential of the solute in this standard state is given the
symbol μº. The chemical potential of the solute at any
molality is now given by:

The activity is defined in terms of the molality, b,
of the solution:

where bº is the molality of the standard state (1 mol kg-1).
Note that, in this definition, the activity coefficient tends
to one as the molality of the solution tends to zero (i.e. as
the solution gets more dilute, its behaviour conforms more with
Henry's Law).
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